| Synthesis,Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido)(4-fluorophenyl)methyl) phosphonate·H_2O |
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| 引用本文： | 高玉焦,邓小艳,彭浩,贺红武.Synthesis,Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido)(4-fluorophenyl)methyl) phosphonate·H_2O[J].结构化学,2014,33(7):985-989. |
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| 作者姓名： | 高玉焦 邓小艳 彭浩 贺红武 |
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| 作者单位： | Key Laboratory of Pesticide and Chemical Biology, Ministry of Education,and College of Chemistry, Central China Normal University, Wuhan 430079, China |
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| 基金项目： | supported by the National Basic Research Program of China(2010CB126100);the National Natural Science Foundation of China(21002037 and 21172090);The research was supported in part by the PCSIRT(No.IRT0953) |
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| 摘 要： | A new crystal of 2-methylpropan-2-aminium methyl((4-fluorobenzamido)(4-fluorophenyl)methyl)phosphonate has been prepared at room temperature and characterized by 1HNMR, 13 C NMR, IR, MS, elemental analysis and X-ray single-crystal determination. The compound crystallizes in monoclinic space group C2/c with a = 20.719(2), b = 11.8559(13), c = 18.176(2) A, β = 94.434(2)°, V = 4451.4(9) A3, Dc = 1.317 Mg/m3, Z = 8, F(000) = 1864 and μ = 0.174 mm-1. The crystal packing is stabilized by intermolecular N–H···O and O–H···O hydrogen bonds, as well as by weak π-π stacking interactions.
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| 关 键 词： | 甲酰氨基 膦酸酯 X射线 氟苯 晶体 苯基 表征 H2O |
Synthesis,Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido) (4-fluorophenyl)methyl)phosphonate·H2O |
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| GAO Yu-Jiao
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DENG Xiao-Yan
,
PENG Hao
,
HE Hong-Wu.Synthesis,Characterization and X-ray Crystal Structure of 2-Methylpropan-2-aminium Methyl ((4-Fluorobenzamido) (4-fluorophenyl)methyl)phosphonate·H2O[J].Chinese Journal of Structural Chemistry,2014,33(7):985-989. |
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| Authors: | GAO Yu-Jiao DENG Xiao-Yan PENG Hao HE Hong-Wu |
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| Institution: | Key Laboratory of Pesticide and Chemical Biology, Ministry of Education,and College of Chemistry, Central China Normal University, Wuhan 430079, China |
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| Abstract: | X-ray crystallography, benzamide, phosphonate |
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| Keywords: | X-ray crystallography benzamide phosphonate |
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