| Synthesis,Structure, and Luminescent Property of a 3-D Zinc Complex { [ZN8II（4-APha）8（CH3COO）8] （CH3CH2OH）2}n① |
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| 引用本文： | 杨华,胡道道.Synthesis,Structure, and Luminescent Property of a 3-D Zinc Complex { [ZN8II（4-APha）8（CH3COO）8] （CH3CH2OH）2}n①[J].结构化学,2014,33(7):1019-1024. |
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| 作者姓名： | 杨华 胡道道 |
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| 作者单位： | [1]College of Chemistry and Chemical Engineering,Yah 'an University, Yah 'an, Shaanxi 716000, China; [2]School of Materials Science and Engineering,Shaanxi Normal University, Xi'an, Shaanxi 710062, China |
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| 基金项目： | Supported by Department of Education of Shaanxi Province(2013JK0664) |
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| 摘 要： | The title complex ZnⅡ8(4-APha)8(CH3COO)8(CH3CH2OH)2]n(1, 4-APha = 4-aminophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a = 39.074(4), b = 9.9645(8), c = 38.846(3) A, β = 136.438 o, V = 10423.1(14) A3, C84H118N16O39Zn8, Mr = 2498.90, Z = 4, Dc = 1.592 g/cm3, μ = 1.900 mm-1, F(000) = 5144, the final R = 0.1036 and wR = 0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha- ligands. The luminescent property of the title complex has been investigated.
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| 关 键 词： | 3-D COO 发光性能 结构 复合物 X射线单晶衍射 合成 元素分析 |
Synthesis,Structure,and Luminescent Property of a 3-D Zinc Complex {[Zn_8~(II)(4-APha)_8(CH_3COO)_8](CH_3CH_2OH)_2}_n |
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| YANG Hua
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HU Dao-Dao.Synthesis,Structure,and Luminescent Property of a 3-D Zinc Complex {[Zn_8~(II)(4-APha)_8(CH_3COO)_8](CH_3CH_2OH)_2}_n[J].Chinese Journal of Structural Chemistry,2014,33(7):1019-1024. |
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| Authors: | YANG Hua HU Dao-Dao |
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| Institution: | 1. College of Chemistry and Chemical Engineering,Yan'an University, Yan'an, Shaanxi 716000, China;School of Materials Science and Engineering,Shaanxi Normal University, Xi'an, Shaanxi 710062, China
2. School of Materials Science and Engineering,Shaanxi Normal University, Xi'an, Shaanxi 710062, China |
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| Abstract: | zinc complex, hydroxamic acftls, 3-D framework, luminescent property |
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| Keywords: | zinc complex hydroxamic acids -D framework luminescent property |
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