| A New Porous Cadmium(Ⅱ) Complex Based on 1,10-Phenanthroline Derivative and Dicarboxylate:Syntheses,Structure, Thermal Behavior and Luminescence |
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| 作者姓名： | 郭胜男 胡永娇 刘洪杰 安雪 邹婷 孔治国 |
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| 作者单位： | [1]Key Laboratory of Preparation andApplications of Environmental FriendlyMaterials, Jilin Normal University, Ministry of Education, Siping 136000, China; [2]Department of Chemistry, Jilin Normal University, Siping 136000, China |
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| 基金项目： | Supported by the Science and Technology Research Projects of the Education Committee of Jilin Province(No.2013206) |
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| 摘 要： | A new porous Cd(Ⅱ) coordination compound, namely, [Cd(bpdc)(L)2]·3H2O(1, L = 11-fluoro-dipyrido[3,2-a:2,3-c]phenazine and bpdc = 1,1-biphenyl-2,2-dicarboxylate) was synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffraction. It crystallizes in tetragonal, space group P4122 with a = 9.8486(4), b = 9.8486(4), c = 45.925(4)A, V = 4454.5(5) 3, Z = 4, C50H29 Cd F2N8O7, Mr = 1004.21, Dc = 1.497 g/cm3, F(000) = 2028, μ(Mo Ka) = 0.562 mm-1, R = 0.0566 and w R = 0.1585. Each Cd(Ⅱ) atom is coordinated by one bpdc anion and two L ligands to give a discrete molecule. Neighboring discrete molecules are stacked by π-π interactions among L ligands, resulting in an interesting 1D supramolecular chain. Moreover, the 1D supramolecular chains are packed with each other to give a porous structure, in which an infinite channel is filled with water molecules. In addition, the thermal behavior and luminescent property of 1 have also been studied.
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| 关 键 词： | 多孔结构 发光性能 二羧酸 邻菲罗啉 合成 衍生物 配合基 热性能 |
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