Frustrated Lewis Pair Activation of an N‐Sulfinylamine: A Source of Sulfur Monoxide |
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| Authors: | Lauren E. Longobardi Vanessa Wolter Prof. Dr. Douglas W. Stephan |
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| Affiliation: | 1. Department of Chemistry, University of Toronto, 80 St. George St, Toronto, Ontario, M5S 3H6 (Canada);2. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia) |
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| Abstract: | Inter‐ and intramolecular P/B frustrated Lewis pairs are shown to react with an N‐sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine–borane‐stabilized sulfur monoxide complexes, and indeed these species act as sources of SO, effecting the oxidation of PPh3 and delivering SO to [RhCl(PPh3)3] and an N‐heterocyclic carbene. |
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| Keywords: | carbenes frustrated Lewis pairs phosphinimine– boranes rhodium sulfur monoxide |
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