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G‐Quartet‐Based Nanostructure for Mimicking Light‐Harvesting Antenna
Authors:Fang Pu  Li Wu  Xiang Ran  Prof. Jinsong Ren  Prof. Xiaogang Qu
Affiliation:1. State Key Laboratory of Rare Earth Resource Utilization and Laboratory of Chemical Biology, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022 (P.R. China);2. University of Chinese Academy of Sciences, Beijing 100039 (P.R. China)
Abstract:Artificial light‐harvesting systems have received great attention for use in photosynthetic and optoelectronic devices. Herein, a system involving G‐quartet‐based hierarchical nanofibers generated from the self‐assembly of guanosine 5′‐monophosphate (GMP) and a two‐step Förster resonance energy transfer (FRET) is presented that mimics natural light‐harvesting antenna. This solid‐state property offers advantages for future device fabrication. The generation of photocurrent under visible light shows it has potential for use as a nanoscale photoelectric device. The work will be beneficial for the development of light‐harvesting systems by the self‐assembly of supramolecular nanostructures.
Keywords:G‐quartets  light harvesting  nanostructures  nucleotides  photocurrent
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