The bis(p-sulfonatophenyl)phenylphosphine-assisted synthesis and phase transfer of ultrafine gold nanoclusters

The behavior of Couette flow of nanofluids composed of negatively-charged nanoparticles dispersed in aqueous NaCl solutions is studied theoretically. The equation for calculating the Couette flow velocity profiles is derived. The induced electric fields and velocity profiles are calculated as a function of key parameters including nanoparticle size and volume fraction. We have found for the first time that the velocity profile of nanofluids containing charged nanoparticles deviates significantly from the classical linear velocity profile for Couette flow. This previously unseen flow phenomenon is attributed to the dominance of the electric field strength induced by the flow of charged nanoparticles. This new mechanism of nanoparticle-induced microfluidic transport could lead to novel microfluidic and tribological applications.