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Some studies on the extraction of plutonium from phosphate containing nitric acid solutions using DBDECMP as extractant
Authors:V B Sagar  M S Oak  S M Pawar  C K Sivaramakrishnan  S K Patil
Institution:(1) Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400 085 Bombay, India
Abstract:Extraction studies have been carried out to explore the feasibility of separation of Pu(IV) from phosphate containing analytical wastes generated in the laboratory. Distribution data on the extraction of Pu(IV) from DBDECMP (di-butyl, N,N-diethylcarbamoyl methyl phosphonate) in xylene from an aqueous nitric acid and its mixture with sulfuric as well as with sulfuric and phosphoric acids were obtained. Based on the data obtained, the conditions for the recovery of plutonium from such waste solutions are suggested.
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