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Extensivity of entropy and modern form of Gibbs paradox
Authors:D Home  S Sengupta
Affiliation:(1) Solid State Physics Research Centre, Physics Department, Presidency College, 700 073 Calcutta, India
Abstract:The extensivity property of entropy is clarified in the light of a critical examination of the entropy formula based on quantum statistics and the relevant thermodynamic requirement. The modern form of the Gibbs paradox, related to the discontinuous jump in entropy due to identity or non-identity of particles, is critically investigated. Qualitative framework of a new resolution of this paradox, which analyses the general effect of distinction mark on the Hamiltonian of a system of identical particles, is outlined.
Keywords:Extensivity of entropy  Gibbs paradox  distinguishability  identical particles  Hamiltonian
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