Dual reactivity of electrochemically generated 2-thiophenaldehyde anion-radicals |
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| Authors: | V. P. Gul'tyai L. M. Korotaeva A. P. Rodionov A. M. Moiseenkov |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The one-electron reduction of 2-thiophenaldehyde in DMF as the medium gives, besides the usual dimerization product of the pinacol type, also 5-( -thienyl)-2-acetoxymethylthiophenaldehyde, which is explained by the dual reactivity of the electrochemically generated anion-radicals.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1150–1153, May, 1981. |
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