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Atmospheric aging of poly[methyl(phenyl)silanediyl] monitored by FTIR spectroscopy
Authors:Oto Meszároš  Pavel Schmidt  Jan Pospíšil  Stanislav Nešpůrek  Ivan Kelnar
Affiliation:Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague, Czech Republic
Abstract:Poly[methyl(phenyl)silanediyl] films were irradiated in ATLAS Weather-O-Meter Ci 3000+ for ca 3 h. Changes in the region of siloxane, carbonyl, hydroxyl, and C-H (aromatic) bands were monitored by FTIR. Main attention was paid to changes in siloxane formation, which could be reduced in the presence of phenolic UV absorber 1 and oxalanilide 3 .
Keywords:formation of siloxane groups  photooxidation  poly[methyl(phenyl)silanediyl]
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