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Kinetic investigations of the unimolecular decomposition of dimethylether behind shock waves
Authors:Ravi Xavier Fernandes   Christa Fittschen  Horst Hippler
Affiliation:(1) Institut für Physikalische Chemie, Universit?t Karlsruhe (TH) and Karlsruhe Institute of Technology (KIT), Kaiserstr. 12., D-76128 Karlsruhe, Germany;(2) Physicochimie des Processus de Combustion et de l’Atmosphère UMR CNRS / USTL 8522, Université des Sciences et Technologies de Lille 1, 59655 Villeneuve d’Ascq, Cedex, France;(3) Present address: Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551-0969, USA
Abstract:The thermal decomposition of dimethylether was studied behind reflected shock waves at total pressures of 0.3 − 1.3 bar in the temperature range 1270 − 1620 K using H-atom detection by Lyman-α resonance absorption spectroscopy at 121.6 nm.
Keywords:Dimethylether  decomposition  H-ARAS  shock tube
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