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Absorption spectra of substituted indoles in stretched polyethylene films
Institution:1. Department of Physics, N.M.S.S.V.N. College, Madurai 625019, Tamil Nadu, India;2. Department of Physics, School of Advanced Sciences, Vellore Institute of Technology (VIT) University, Vellore, Tamil Nadu, India;1. School of Medicine and Pharmacy, Ocean University of China, Qingdao 266003, PR China;2. Laboratory for Marine Drugs and Bioproducts of Qingdao National Laboratory for Marine Science and Technology, Qingdao 266003, PR China;3. Key Laboratory of Glycoscience & Glycotechnology of Shandong Province, Qingdao 266003, PR China;4. Key Laboratory of Marine Drugs, Ministry of Education of China, Qingdao 266003, PR China
Abstract:The stretched film technique has been used to resolve the two overlapping 1La and 1Lb transitions in the absorption spectra of some substituted indoles. The substituent effects on the absorption spectrum of indole, N-ethyl indole, 3-methyl indole and 7-methyl indole are discussed. The directions of the transition moments of these indoles with respect to the long molecular axis have been determined and the differences were attributed to the changes in the molecular geometry on excitation. The vibronic structure in the absorption spectra of these indoles is also considered.
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