Molar excess enthalpies of cis-decalin + benzene, + toluene, +isooctane and +heptane at 298.15 K |
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| Institution: | 1. College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;2. Energy Engineering, Division of Energy Science, Luleå University of Technology, 97187 Luleå, Sweden;1. Department of Chemistry, United States Naval Academy, Annapolis, MD 21402, United States;2. Department of Physics, United States Naval Academy, Annapolis, MD 21402, United States;1. Toxicology & Environmental Sciences Division, ExxonMobil Biomedical Sciences, Inc., 1545 US Highway 22 East, Annandale, NJ, 08801-3059, USA;2. Toxicology & Environmental Sciences Division, ExxonMobil Biomedical Sciences, Inc., 2777 Springwood Village Parkway, Spring, Texas 77339-1425, USA;3. Corporate Strategic Research, ExxonMobil Research and Engineering 1545 US Highway 22 East, Annandale, NJ, 08801-3059, USA |
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| Abstract: | Molar excess enthalpies HE of cis-decalin + benzene, +toluene, +isooctane and +heptane mixtures have been measured by an LKB flow microcalorimeter at 298.15 K. The experimental results are analyzed using the Flory-Patterson-Prigogine theory. The isomer effect of decalin molecule and the effect of the molecular size and shape of the component molecules are discussed. |
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