Tetrahydroboratobis(triphenylphosphine)copper(I): a vibrational spectroscopic study |
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| Institution: | 1. Department of Chemistry, La Trobe University, Bundoora, Victoria 3083, Australia;1. ISISE, Departamento de Engenharia Civil, Universidade de Coimbra, Rua Luís Reis Santos – Pólo II da Universidade, 3030-788 Coimbra, Portugal;2. CERIS, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal;1. School of Physics, University of Electronic Science and Technology of China, Chengdu, Sichuan, 610054, China;2. Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu, 610054, China;3. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, CAS, Zhongshan Road 457, 116023, Dalian, China;4. Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan, 48109, United States;5. School of Materials Science and Engineering, The University of New South Wales, Sydney, 2052, Australia;1. Center for Environmental Nanoscience and Risk, Department of Environmental Health Sciences, Arnold School of Public Health, University of South Carolina, Columbia, SC, United States;2. Department of Civil and Environmental Engineering, University of California Los Angeles, California, USA;3. Southern California Coastal Water Research Project, Costa Mesa, CA, United States;4. Virginia Tech National Center for Earth and Environmental Nanotechnology (NanoEarth), 1991 Kraft Dr., Blacksburg, VA, 24061, USA;5. Department of Civil, Structural and Environmental Engineering, University at Buffalo, Buffalo, NY, 14260, United States;1. Centre for Advanced Optoelectronic Functional Materials Research, Key Laboratory for UV Light-Emitting Materials and Technology of the Ministry of Education, Northeast Normal University, Changchun 130024, People’s Republic of China;2. National Demonstration Center for Experimental Physics Education, Northeast Normal University, Changchun 130024, People’s Republic of China;1. Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Material Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China;2. Manufacturing System Research, GM Global R&D, Warren, MI 48092, USA |
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| Abstract: | Application of infrared and Raman spectroscopy together with hydrogen—deuterium substitution has allowed identification of at least seven of the twelve fundamental vibrational frequencies expected for the double bridge CuBH4 unit in tetrahydroboratobis(triphenylphosphine)copper(I). Limited assignments for the AgBH4 unit in the analogous silver compound, based on infrared data for the hydride deuteride, are also presented. |
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