Vibrational spectra of imidazoline-2-thione and imidazoline-2-one |
| |
Institution: | 2. Department of Chemistry, University of Sheffield, Sheffield, United Kingdom |
| |
Abstract: | Raman and infrared spectra of imidazoline-2-thione (IMZT) and imidazoline-2-one (IMZO) have been recorded. Normal coordinate analyses have been performed for all the fundamental vibrations of IMZT, IMZT-d2 and IMZO employing a Urey—Bradley potential function supplemented with valence type force constants for the out of plane modes. The results of the vibrational analyses are discussed in relation to the assignments in related molecules. The vibrational assignments for IMZT and IMZO have been compared with those in structurally similar molecules and the need to obtain more reliable band assignments for some of the molecules considered is emphasised. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|