Synthesis and reactivity of metal-containing monomers 49. Synthesis and structure of low-valence transition metal acrylates and their polymers |
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| Authors: | G. I. Dzhardimalieva I. N. Ivleva Yu. M. Shul'ga E. N. Frolov A. D. Pomogailo |
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| Affiliation: | (1) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | The methods for synthesis of Cu1+, Fe2+, Cr2+, and V3+ acrylates were elaborated. The compounds obtained were characterized by elemental analyses, data of IR, X-ray photoelectron, and Mössbauer spectroscopy, magnetochemistry, and mass spectrometry. Polymeric products were obtained by liquid-phase radical polymerization of metal acrylates. Changes in the electronic state of the ions and their nearest ligand environment during polymerization were observed. |
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| Keywords: | metal acrylates metal in lowest oxidation state metal polyacrylates synthesis structure |
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