Substitution Effects on the Photophysical Characteristics of the Salicylic Anion |
| |
| Authors: | Hem C Joshi Cees Gooijer Gert van der Zwan |
| |
| Institution: | (1) Department of Analytical Chemistry and Applied Spectroscopy, Laser Centre, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands;(2) Institute for Plasma Research, Bhat, Gandhinagar-, 382428, India |
| |
| Abstract: | Spectral and photophysical properties of substituted salicylic anions are investigated by steady-state and time-resolved fluorescence spectroscopy for a variety of electron donating substituents at the positions para to the hydroxyl and carboxylic groups. Next to the usual excited-state intramolecular proton transfer in aqueous solution, an excited-state intermolecular proton transfer is found to be responsible for the dual emission observed in the case of 5-aminosalicylic anions. |
| |
| Keywords: | Salicylic anion substitution ESIPT Stokes shift |
| 本文献已被 SpringerLink 等数据库收录！ |
|
