| Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Trichloroacetonitrile (CI3CCN) and Sodium Hydride |
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| 引用本文： | SHI Wei-Feng JIANG Nan WANG Jian-Bo. Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Trichloroacetonitrile (CI3CCN) and Sodium Hydride[J]. 有机化学, 2003, 23(Z1): 17-17 |
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| 作者姓名： | SHI Wei-Feng JIANG Nan WANG Jian-Bo |
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| 作者单位： | SHI Wei-Feng（Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871） JIANG Nan（Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871） WANG Jian-Bo（Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemical Biology, College of Chemistry, Peking University, Beijing 100871） |
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| 摘 要： | In the process of preparing α-diazo carbonyl compound 2 by imidation of 1, we unexpectedly observed a direct conversion of the hydroxyl group into trichloroacetylamino group. In this presentation, we report this unprecedented reaction, as well as the Rh2(OAc)4-catalyzed reaction of the resulting β-(trichloroacetyl)amino β-diazo carbonylcompounds 3. [ 1]
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Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Trichloroacetonitrile (CI3CCN) and Sodium Hydride |
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| SHI Wei-feng,JIANG Nan,WANG Jian-Bo. Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Trichloroacetonitrile (CI3CCN) and Sodium Hydride[J]. Chinese Journal of Organic Chemistry, 2003, 23(Z1): 17-17 |
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| Authors: | SHI Wei-feng JIANG Nan WANG Jian-Bo |
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| Abstract: | In the process of preparing α-diazo carbonyl compound 2 by imidation of 1, we unexpectedly observed a direct conversion of the hydroxyl group into trichloroacetylamino group. In this presentation, we report this unprecedented reaction, as well as the Rh2(OAc)4-catalyzed reaction of the resulting β-(trichloroacetyl)amino β-diazo carbonylcompounds 3. [ 1] |
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