Reaction of 8-(dimethylamino)methyl-1-naphthyl phenyl silanethione with phosphorus ylides |
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| Authors: | I. V. Borisova N. N. Zemlyansky A. K. Shestakova Yu. A. Ustynyuk |
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| Affiliation: | (1) State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, 38 sh. Entuziastov, 111123 Moscow, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The title silanethione reacts with phosphorus ylides under conditions of kinetic control to give betaines containing a linear fragment. Under conditions of thermodynamic control, the derivatives of phosphonium 1-silaacenaphthene-1-thiolate are formed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2140–2141, December, 1993. |
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| Keywords: | linear organosilicon betaines alkylidenephosphoranes silanethione |
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