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Reactions of pentafluorophenylxenon(II) hexafluoroarsenate [C6F5Ze] [AsF6] with halide anions in acetonitrile |
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| Authors: | H J Frohn A Klose V V Bardin A J Kruppa T V Leshina |
| Institution: | a Fachgebiet Anorganische Chemie, Universität Duisburg, Lotharstr. 1, D-47048, Duisburg, Germany b Institute of Organic Chemistry, 630090, Novosibirsk, Russia c Institute of Chemical Kinetics and Combustion, 630090, Novosibirsk, Russia |
| Abstract: | Reactions of C6F5Xe]+ AsF6]− in acetonitrile with halide anions X− show different results depending on X. If X = I, Br or Cl, then C6F5X is obtained. If X = F, then C6F5H and C6F5---C6F5 are produced, and if X = HF2, then C6F6, C6F5H and C6F5---C6F5 are formed. |
| Keywords: | Pentafluorophenylxenon(II) hexafluoroarsenate Halide ions Acetonitrile solvent NMR spectroscopy CIDNP effect Reactions |
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