Selective oxidation of organic compounds using pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] ( PSFC ) |
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| Authors: | Ahmad R. Bekhradnia Forohe Zahir Sattar Arshadi |
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| Affiliation: | (1) Department of Chemistry, Ramakrishna Mission Vivekananda College, Mylapore, Chennai, 600004, India;(2) Department of Chemistry, Madras Christian College, Tambaram, Chennai, 600059, India; |
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| Abstract: | Efficient selective oxidation of primary, secondary, and benzylic alcohols to the corresponding carbonyl compounds by a new chromium oxidizing reagent, pyridinium-1-sulfonate fluorochromate, C5H5NSO3H [CrO3F] (PSFC) is reported. Various cholesterol derivatives were easily converted to related oxocholesterol from allylic oxidation at lower temperature in comparison to other general oxidants. This oxidation procedure is simple and affords good yields. |
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