N,N-dialkylaminomethyltributyltins as precursors of (N,N-dialkylaminomethyl) ketones |
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| Affiliation: | 1. Department of Organic Chemistry, Institute of Chemistry, Saint Petersburg State University, Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia;2. Department of Organic Chemistry, Saint Petersburg Institute of Technology (Technical University), Moskovskiy pr. 26, 190013 Saint Petersburg, Russia;3. Department of Chemistry, Saint Petersburg State Forest Technical University, Institutsky per., 5, Saint Petersburg 194021, Russia;1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prospect, 119991, Moscow, Russia;2. D. I. Mendeleev University of Chemical Technology, 9 Miusskaya square, 125047, Moscow, Russia;1. Medicinal Chemistry Research Laboratory, Department of Pharmacy, Birla Institute of Technology & Science, Pilani 333031, Rajasthan, India;2. Laboratory of Molecular Immunopharmacology, Key Laboratory of Animal Models and Human Disease Mechanisms of Chinese Academy of Sciences and Yunnan Province, Kunming Institute of Zoology, Chinese Academy of Sciences, Kunming, Yunnan 650223, PR China;1. Instituto Multidisciplinario de Biología Vegetal (IMBIV – CONICET), Cátedra de Química Orgánica, ICTA, Facultad de Ciencias Exactas, Físicas y Naturales, Universidad Nacional de Córdoba, Av. Vélez Sarsfield 1611, X5016GCA, Córdoba, Argentina;2. IDTQ, Grupo Vinculado PLAPIQUI (CONICET), Facultad de Ciencias Exactas Físicas y Naturales - Universidad Nacional de Córdoba, Av. Veléz Sarsfield 1611, X5016GCA, Córdoba, Argentina |
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| Abstract: | (N,N-dialkylaminoethyl)ketones have been obtained in good yields (64–87%) by reacting (N,N-dialkylaminoethyl) tributyltins with acyl chlorides. The mildness of the experimental conditions is compatible with the presence of functional groups like acetals, aldehydes or nitriles. |
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