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A simple and efficient preparation of sulfinyl chlorides from disulfides and sulfuryl chloride
Affiliation:1. School of Biosciences, University of Exeter, Exeter EX4 4QD, UK;2. University of Utrecht, Padualaan 8, Utrecht 3584 CH, The Netherlands;1. National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, No. 36 Lushan Road, Changsha 410081, China;2. Guangzhou Institutes of Biomedicine and Health, Chinese Academy of Sciences, No. 190 Kaiyuan Avenue, Guangzhou Science Park, Guangzhou 510530, China;1. National Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Huaxi District, Guiyang 550025, China;2. School of Chemistry, Chemical Engineering, and Biotechnology, Nanyang Technological University, Singapore 637371, Singapore;1. Fakultät für Chemie und Biochemie, Ruhr-Universität Bochum, Universitätsstraße 150, ZEMOS 2.27, 44801, Bochum, Germany;2. Micro- & Nano-Electrochemistry, Center for Electrochemical Sciences (CES), Ruhr-Universität Bochum, ZEMOS 1.45, Universitätsstr. 150, 44801, Bochum, Germany
Abstract:Disulfides react with sulfuryl chloride in the presence of acetic acid to form. the corresponding sulfinyl chlorides in nearly quantitative yield.
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