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Regiocontrolled synthesis of allylsilanes by means of rhodium(I) or iridium(I) catalyzed isomerization of olefins
Affiliation:1. Laboratory of Neuropharmacology, Fudan University School of Pharmacy, Shanghai 201203, PR China;2. School of Biomedical Sciences, Faculty of Medicine, The Chinese University of Hong Kong, NT, Hong Kong;1. Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu Plentas 19, LT50254, Kaunas, Lithuania;2. Department of Photonics Engineering, Yuan Ze University, Chung-Li 32003, Taiwan;1. School of Mechanics and Engineering Science, Zhengzhou University, Zhengzhou, Henan, 450001, PR China;2. School of Science, Dalian Maritime University, Dalian, Liaoning, 116026, PR China;3. State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui, 230026, PR China;1. Laboratory of Aquatic Natural Products Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Bunkyo-ku, Tokyo 113-8657, Japan;2. Sugashima Marine Biological Laboratory, Graduate School of Science, Nagoya University, Sugashima-cho, Toba-shi, Mie 517-0004, Japan;3. Center for Marine and Coastal Studies, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia;4. Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Bukyo-ku, Tokyo 113-8657, Japan;1. N. D. Zelinsky Institute of Organic Chemistry, RAS, 47 Leninsky Prospect, 119991, Moscow, Russian Federation;2. Faculty of Science, RUDN University, 6 Miklukho-Maklay Street, 117198, Moscow, Russian Federation;3. A. N. Nesmeyanov Institute of Organoelement Compounds, RAS, 28 Vavilov Street, 119991, Moscow, Russian Federation;4. N. K. Koltzov Institute of Developmental Biology, RAS, 26 Vavilov Street, 119334, Moscow, Russian Federation
Abstract:Rhodium(I) or iridium(I) catalyzed migration of double-bond has been successfully applied to the regiocontrolled synthesis of allylsilane from olefin silylated at a remote sp carbon.
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