Silafunctional compounds in organic synthesis. 30. Intramolecular hydrosilation of alkenyl alcohols: A new approach to the regioselective synthesis of 1,2- and 1,3-diols |
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| Affiliation: | 1. Dr. M.G.R Educational and Research Institute, Chennai-600029, Tamil Nadu, India;2. Department of Chemistry and Physics, Monmouth University, West Long Branch, NJ, 07764, USA;1. Department of Chemistry, Virginia Tech, Blacksburg, VA 24061-0212, USA;2. Department of Chemistry & Biochemistry, The Ohio State University, Columbus, OH 43210-1340, USA;1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152-8552, Japan;2. Research Center of Integrative Molecular Systems (CIMoS), Institute for Molecular Science, National Institutes of Natural Science, Myodaiji, Okazaki, Aichi, 444-8787, Japan;3. Department of Structural Molecular Science, the Graduate University of Advanced Sciences, Myodaiji, Okazaki, Aichi, 444-8787, Japan;4. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan;1. Division of Organic Chemistry, National Chemical Laboratory (CSIR-NCL), Pune 411008, India;2. Combichem Bioresource Centre, National Chemical Laboratory, Pune, India |
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| Abstract: | Intramolecular hydrosilation of allyl and homoallyl alcohols and the subsequent oxidative cleavage of the resultant carbon—silicon bond have provided a new approach to the regio-controlled synthesis of 1,2- and/or 1,3-diols. |
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