Tin-directed nazarov cyclizations: A versatile route to cyclopentenoids |
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| Affiliation: | 1. Center for Nano Science and Engineering, Indian Institute of Science, Bangalore 560012, India;2. Department of Chemical Engineering, M. S. Ramaiah Institute of Technology, Bangalore, India;3. Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India;4. Department of Chemical Engineering, Indian Institute of Science, Bangalore 560012, India;1. Vanderbilt University, Department of Pharmacology, Division of Clinical Pharmacology, USA;2. Vanderbilt University, Department of Chemistry, USA;1. Institute of Analytical Chemistry of the ASCR, v. v. i., Veveří 97, 60200 Brno, Czech Republic;2. Faculty of Pharmacy, P.O. Box 56, 00014 University of Helsinki, Finland;3. Steno Diabetes Center, Niels Steensens Vej 2, 2820 Gentofte, Denmark;4. Department of Chemistry, P.O. Box 55, 00014 University of Helsinki, Finland;1. Genentech, Inc, 1 DNA Way, South San Francisco, CA 94080, USA;2. Charles River Discovery Research Services UK Limited, 7-9 Spire Green Centre, Flex Meadow, Harlow Essex CM19 5TR, United Kingdom;3. WuXi AppTec Co, Ltd., 288 Fute Zhong Road, Waigaoqiao Free Trade Zone, Shanghai 200131, PR China;1. Department of Chemistry, Faculty of Science, King Khalid University, P. O. Box 9004, Abha 61413, Saudi Arabia;2. Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany;3. Egyptian Organization for Biological Products and Vaccines [VACSERA Holding Company], 51 Wezaret El-Zeraa St., Agouza, Giza, Egypt |
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| Abstract: | The preparation of 1-(tri-butylstanniyl-1,4-pentadien-3-ones and their efficient Nazarov cyclizations to cyclopentenones, including a PGA analogue, are described. |
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