Mechanism of the oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium cation |
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| Affiliation: | 1. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland;1. Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture & Research Center of Sustainable Energy and Nanotechnology, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan;2. Department of Occupational Safety and Health, China Medical University, 91 Hsueh-Shih Road, Taichung 40402, Taiwan;3. Department of Biotechnology, National Formosa University, Yunlin 63208, Taiwan;1. Department of Chemistry, Faculty of Philosophy Sciences and Letters at Ribeirão Preto, University of São Paulo, 14040-901 Ribeirão Preto, SP, Brazil;2. Department of Biochemistry and Immunology, Ribeirão Preto Medical School, University of São Paulo, 14040-901 Ribeirão Preto, SP, Brazil;3. Department of Biology, Faculty of Philosophy Sciences and Letters at Ribeirão Preto, University of São Paulo, 14040-901 Ribeirão Preto, SP, Brazil;4. Departments of Chemistry and Materials Science and Engineering, University of Utah, Salt Lake City, UT 84112, United States of America |
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| Abstract: | Simple Hammett studies, hydrogen isotope effects, and attempted preparation of proposed transient intermediates are used to probe the mechanism of oxidation of alcohols by 2,2,6,6-tetramethylpiperidine nitrosonium ion. |
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