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Studies on the Pd catalyzed reaction of perfluoroalkyl and polyfluoroalkyl iodides with tertiary amines
Affiliation:1. College of Marine Technology and Environment, Dalian Ocean University, Dalian 116023, China;2. Laboratory for coastal marine eco-environment process and carbon sink of Hainan province/Yazhou Bay Innovation Institute, Hainan Tropical Ocean University, Sanya 572022, China;3. National Marine Environmental Monitoring Center, Dalian 116023, China;4. College of Marine Ecology and Environment, Shanghai Ocean University, Shanghai 201306, China;5. NCS Testing Technology Co., Ltd., Beijing 10081, China;1. Joint Research Centre for Protective Infrastructure Technology and Environmental Green Bioprocess, Department of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin 300384, China;2. Tianjin Key Laboratory of Aquatic Science and Technology, Tianjin Chengjian University, Jinjing Road 26, Tianjin 300384, China;3. Centre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, University of Technology Sydney, Sydney, NSW 2007, Australia;4. School of Civil and Environmental Engineering, University of Technology Sydney, NSW 2007, Australia
Abstract:Pd catalyzed reaction of perfluoroalkyl and polyfluoroalkyl iodides with tertiary amines gave enamines(1) which on acid hydrolysis afforded enaminones(2), or aldehydes(3).
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