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Photoreaction of 9-dicyanomethylene-1,2,3,4-tetrahydro-1,4-methanonaphthalene: the 1,3-carbon migrations and the ethylene extrusion to dicyanoisobenzofulvene
Affiliation:1. Computer Science department, Faculty of Sciences, Lebanese University, Beirut, Lebanon;2. American University of the Middle East, College of Engineering and Technology, Egaila, Kuwait;3. TICKET lab, Faculty of Engineering, Antonine University, Baabda, Lebanon;1. Departamento de Desarrollo Tecnológico, Centro Universitario Regional Del Este, Universidad de la República, Uruguay;2. Departamento de Ecología y Gestión Ambiental, Centro Universitario Regional Del Este, Universidad de la República, Uruguay;3. Grupo de Análisis de Compuestos Traza, Departamento de Química Orgánica, Facultad de Química, Universidad de la República, Uruguay;1. Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau SAR, China;2. Department of Civil Engineering, Qingdao Technological University, Qingdao, 266033, China;3. Department of Civil Engineering, Mirpur University of Science and Technology, Allama Iqbal Road, Mirpur, AJK, 10250, Pakistan;4. XJTU-Oxford International Joint Laboratory for Catalysis, School of Chemical Engineering and Technology, Xi''an Jiaotong University, Xi''an, 710049, China;1. College of Mechanical and Electronic Engineering, Shandong University of Science and Technology, 266590 Qingdao, Shandong Province, China;2. National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, School of Energy and Power Engineering, Shandong University, 250061 Jinan, Shandong Province, China
Abstract:
Irradiation of 9-dicyanomethylene-1,2,3,4-tetrahydro-1,4-methanonaphthalene gave 3,3-dicyano-1,2,3,8b-tetrahydrocyclopent [a] indene and 2-dicyanomethylene-2H-indene.
Keywords:
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