The reactions of flavin analogues and other heterocycles as models for bacterial bioluminescence |
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| Affiliation: | 1. Department of Synthetic Natural Products Chemistry and Medicinal Research Laboratories, School of Pharmacy, Kitasato University, 5–9–1 Shirokane, Minato-ku, Tokyo 108–8641, Japan;2. Kitasato Institute for Life Sciences, Kitasato University, Tokyo 108-8641, Japan |
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| Abstract: | The reactions of 10a-peroxyflavins have been examined to increase understanding of the oxidative and chemiluminescent reactions catalysed by the flavin co-enzymes. A remarkable series of structural requirements in the peroxides used has been uncovered, and in addition to serving as models for the mechanism of bacterial luciferase, they constitute a set of new chemiluminescent reactions. |
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