Synthetic approach to the total synthesis of fumitremorgins II synthesis of optically active pentacyclic intermediates and their dehydrogenation |
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| Affiliation: | 1. Departamento de Química Inorgánica y Analítica, E.S.C.E.T., Universidad Rey Juan Carlos, 28933 Móstoles, Madrid, Spain;2. Institute of Chemistry, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Straße 2, D-06120 Halle, Germany;3. Institute for Biological Research “Sinisa Stankovic”, University of Belgrade, Bulevar despota Stefana 142, 11060 Belgrade, Serbia;4. Faculty of Pharmacy, European University, Trg mladenaca 5, 21000 Novi Sad, Serbia;1. Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China;2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China;1. Departamento de Química Inorgánica, Facultad de Química y de Farmacia, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Macul, Santiago, Chile;2. Departamento de Ciencias Químicas y Biológicas, Universidad Bernardo O`Higgins, General Gana 1702, Santiago, Chile;3. Organisch-Chemisches Institut, Westfälische Wilhelm-Universität, Corrensstrasse 40, 48149 Münster, Germany |
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| Abstract: | Optically active pentacycles ( 13–18 ) were synthesized from L- and D-tryptophans, two of which ( 13 and 15 ) were alkylated and dehydrogenated to 21 and 22, respectively. |
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