Crystal structures of two syn bent tetraalkylhydrazines,their radical cations,and a dication |
| |
| Affiliation: | 1. Molecular Functional Imaging Lab, Advanced Centre for Treatment, Research and Education in Cancer (ACTREC), Tata Memorial Centre, Kharghar, Navi Mumbai, India;2. Chilakapati Laboratory, Advanced Centre for Treatment, Research and Education in Cancer (ACTREC), Tata Memorial Centre, Kharghar, Navi Mumbai, India;3. NanoBios Lab, Department of Biosciences and Bioengineering, Indian Institute of Technology Bombay, Powai, Mumbai, India;4. Department of Life Sciences, Homi Bhaba National Institute, Mumbai, India;1. Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, College of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Zigong 643000, PR China;2. Department of Chemistry, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106, United States;3. Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China |
| |
| Abstract: | The crystal structures of 2,7-diazatetracyclo[6.2.2.23,6.02.7]tetradec-4-ene, 2, its cation radical nitrate salt 2+, NO3-, 2,7-diazatetracyclo[6.2.2.23,6.03,7]tetradecane, 3, its dication dihexafluorophosphate salt 32+(PF6-)2, and a low quality structure of the monocation radical tosylate salt of 3 are reported and compared with MNDO calculations of these structures. Cations 2+ and 3+ are found to be significantly syn bent at nitrogen, and the dication 32+ has a longer N-N distance than its azo analogue, 2,3-diazabicyclo [2.2.2]oct-2-ene (11). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
