PdCl2(MeCN)2-catalyzed carbonylation of diethylamine with carbon dioxide: Selective synthesis of tetraethylurea and diethylformamide |
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| Affiliation: | 1. Department of Applied Chemistry, Faculty of Engineering, Kyushu University, Hakozaki, Fukuoka 812, Japan;2. Department of Industrial Chemistry, Faculty of Science and Technology, Saga University, Honjocho, Saga 840, Japan;1. Department of Physics, Fergusson College, Savitribai Phule Pune University, Pune 411004, India;2. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;3. Health Physics Division, BARC, Mumbai 400085, Maharashtra, India;4. Ex-BARC Scientist, B-6, Ameya Co-op. Housing Society, Sector 9-A, Vashi, Navi Mumbai 400703, India;5. Department of Physics and Astrophysics, University of Delhi, Delhi 110007, India;6. Department of Physics, Savitribai Phule Pune University, Pune 411007, India;1. Department of Pharmacology, Faculty of Pharmacy, Elmergib University, Alkhoms, Libya;2. School of Biomedical Sciences and Pharmacy, University of Newcastle, Callaghan, NSW, 2308, Australia;3. Children''s Cancer Institute, Lowy Cancer Research Centre, UNSW Australia, Randwick, NSW 2031, Australia;4. Hunter Medical Research Institute, New Lambton, New South Wales, 2305, Australia;5. Hunter Haematology Research Group, Calvary Mater Newcastle Hospital, Waratah, NSW, 2298, Australia;6. Translational Research Institute, Henan Provincial People''s Hospital, Zhengzhou University, 450053, Zhengzhou, China;7. School of Environmental and Life Sciences, University of Newcastle, NSW, 2258, Australia;1. School of Environmental Science and Engineering, Collaborative Innovation Center for Marine Biomass Fibers, Materials and Textiles of Shandong Province, Qingdao University, Qingdao, 266071, PR China;2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan, 030001, PR China;3. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, 266590, PR China |
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| Abstract: | 
The reaction of diethylamine with carbon dioxide (CO2) with PdCl2(MeCN)2 as a catalyst gives tetraethylurea(1) or diethylformamide(2) selectively under mild reaction conditions by employing the PPh3/CCl4/MeCN and the HCOONa/methyl cellosolve systems, respectively. |
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