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Addition of trimethylsilyl cyanide to allenes with the aid of a palladium or nickel catalyst
Affiliation:1. Molecular Biomimetics, Department of Chemistry-Ångström, Uppsala University, Uppsala, Sweden;2. Physical Chemistry, Department of Chemistry-Ångström, Uppsala University, Uppsala, Sweden
Abstract:The reaction of allenes with trimethylsilyl cyanide in the presence of a palladium or nickel catalyst provides functinalized vinylsilanes in good yields.
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