Total synthesis of optically active integerrimine,a twelve-membered dilactonic pyrrolizidine alkaloid of retronecine type. III. Regioselective elaboration of the unsymmetrical twelve-membered dilactone and total synthesis of (-)-integerrimine |
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Affiliation: | 1. Dept. of CA, Siksha ‘O’ Anusandhan deemed to be University, Bhubaneswar, Odisha, 751030, India;2. Dept. of Chemistry, Siksha ‘O’ Anusandhan deemed to be University, Bhubaneswar, Odisha, 751030, India;1. Institute for Plant Biology, TU Braunschweig, 38106 Braunschweig, Germany;2. Yasouj University, Yasouj, Kohgiluyeh Va Boyer Ahmad, Iran |
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Abstract: | The first enantioselective synthesis of optically active integerrimine, the twelve-membered dilactonic pyrrolizidine alkaloid has been achieved. |
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