Studies directed towards the synthesis of taxane diterpenes: A remarkable rearrangement |
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| Affiliation: | 1. Institute of Traditional Chinese Medicine & Natural Products, College of Pharmacy, Jinan University, Guangzhou 510632, PR China;2. College of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, Shenyang 110016, PR China;3. State-Province Key Laboratory of Biomedicine-Pharmaceutics of China, Department of Pharmacology, Harbin Medical University, Harbin 150086, PR China |
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| Abstract: | Acid-catalyzed fragmentation of the intramolecular dioxolenone photocycloaddition product 9 leads not to 10, the desired taxane skeleton, but instead to the remarkable rearrangement product 11. |
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