Synthesis of both the enantiomers invictolide,a pheromone component of the red imported fire ant |
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| Affiliation: | 1. Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113 Japan;1. Department of Chemistry, University College of Science, 92, Acharya Prafulla Chandra Road, Kolkata 700009, West Bengal, India;2. Department of Chemistry, Bidhannagar College, EB-2, Sector-1, Salt Lake, Kolkata 700064, India;3. Department of Chemistry, The University of Reading, Whiteknights, Reading RG66AD, UK;1. Southern Scientific Center of Russian Academy of Sciences, Rostov on Don 344006, Russian Federation;2. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov on Don 344090, Russian Federation;1. Global Discovery Chemistry, Novartis Institutes for BioMedical Research, 250 Massachusetts Avenue, Cambridge, MA 02139, United States;2. Cardiovascular and Metabolism, Novartis Institutes for BioMedical Research, 100 Technology Square, Cambridge, MA 02139, United States;1. Chemical and Metallurgical Engineering and Chemistry, Murdoch University, Western Australia 6150, Australia;2. Department of Chemistry, Memorial University, St. John’s, Newfoundland A1B 3X7, Canada |
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| Abstract: | Both the enantiomers of invictolide [3,5-dimethyl-6-(1'-methylbutyl)-tetrahydro-2H-pyran-2-one] were synthesized in 17 steps from propargyl alcohol. |
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