A new electrophilic addition to acetylenes. Synthesis of 1,2-iodofunctionalized olefins |
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| Affiliation: | 1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St, 664033 Irkutsk, Russia;2. Limnological Institute, Siberian Branch of the Russian Academy of Sciences, 3 Ulan-Batorskaya St, 664033 Irkutsk, Russia;1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. I. M. Sechenov First Moscow State Medical University, 119991 Moscow, Russian Federation;3. All-Russian Research Institute of Phytopathology, 143050 Bol''shiye Vyazemy, Moscow Region, Russian Federation |
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| Abstract: | Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate (1) in the presence of a wide variety of nucleophiles (F, Cl, Br, I, SCN, pyridine, OAc, anisole, H) to give 1,2-iodofunctionalized olefins (4). |
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