Spin trapping reactions with nitric oxides. III. Alkoxyalkylnitroxides and new nitrogen centered radicals |
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| Affiliation: | 1. Eötvös Loránd University, Department of Chemical Technology, H-1088 Budapest, Múzeum krt. 6-8, Hungary;1. Department of Chemistry, The University of Akron, Akron, OH 44325-3601, USA;2. Department of Chemistry, Ashland University, 401 College Ave., Ashland, OH 44805, USA;1. Division of Gastroenterology, Department of Medicine, Northwell Health, 270-05 76th, Avenue, New Hyde Park, NY 11040, USA;2. Department of Medicine, Zucker Hofstra Northwell School of Medicine, Sandra Atlas Bass Center for Liver Diseases, Northwell Health, 400 Community Drive, Manhasset, NY 11030, USA;1. Martin-Luther-University Halle-Wittenberg, Organic Chemistry, Kurt-Mothes-Str. 2, D-06120, Halle (Saale), Germany;2. University of Nizwa, Natural and Medical Sciences Research Center, P.O. Box 33, Birkat Al Mauz, Nizwa, 616, Oman;1. Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400076, India;2. Discipline of Chemistry, Indian Institute of Technology Indore, Indore 452 017, India |
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| Abstract: | Subsequent trapping of photochemically generated alkyl and alkoxy radicals by nitric oxide yields alkoxyalkylnitroxide radicals. New types of nitrogen centered radicals have been detected and tentatively explained by reactions of nitrogen oxides N2O, NO, NO2, N2O3, N2O4 with alkyl and peroxide radicals. |
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