Effect of the Reaction Products on the Rate of Oxidation of Crotonaldehyde |
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| Authors: | Fedevich O E Levush S S Fedevich E V Kit Yu V |
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| Institution: | (1) L'vivs'ka politekhnika National University, ul. Sagaidachnogo 14b, L'vov, 79014, Ukraine;(2) L'vov State Agrarian University, L'vov, Ukraine |
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| Abstract: | Study of the oxidation of crotonaldehyde revealed an appreciable inhibitory effect of the products on the process. Analysis of the kinetic data obtained over a wide range of reaction conditions (c
0 1.5-3.3 M, pO2 1-16 atm, T 293-309 K) showed that the overall oxidation process (with account taken of the inhibitory effect of the products) is described by the equation: W
CA = k*ap
c
CA (pO2)0.6 (1 + 0.17 c
CA)-
1, where k*ap is the apparent rate constant, and c
CA is the decrease of the aldehyde concentration by a moment . |
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| Keywords: | |
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