| Synthesis and Crystal Structure of a Novel Hydrogen-Bonded Three-Dimensional Polymer [Zn(1,4-benzenedicarboxylate)-(pyridine)·H_2O]_n |
| |
| 引用本文： | 王瑞虎
,洪茂椿
,翁家宝
,曹荣
,罗军华.Synthesis and Crystal Structure of a Novel Hydrogen-Bonded Three-Dimensional Polymer [Zn(1,4-benzenedicarboxylate)-(pyridine)·H_2O]_n[J].中国化学,2002,20(10):1124-1128. |
| |
| 作者姓名： | 王瑞虎 洪茂椿 翁家宝 曹荣 罗军华 |
| |
| 作者单位： | WANG，Rui-Hu HONG，Mao-Chun WENG，Jia-Bao CAO，Rong LUO，Jun-HuaState Key Laboratory of Structural Chemistry，Fujian Institute of the Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| |
| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 982 5 10 3) ,theNaturalScienceFoundation (No .8982 0 0 3)ofFujianProvinceandChineseAcademyofSciences |
| |
| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＤｅｓｉｇｎａｎｄｓｙｎｔｈｅｓｅｓｏｆｎｏｖｅｌｓｕｐｒａｍｏｌｅｃｕｌａｒｃｏｍ ｐｌｅｘｅｓｗｉｔｈｕｎｕｓｕａｌａｎｄｔａｉｌｏｒａｂｌｅｓｔｒｕｃｔｕｒｅｓａｒｅｆｕｎｄａ ｍｅｎｔａｌｓｔｅｐｓｉｎｄｉｓｃｏｖｅｒｙａｎｄｆａｂｒｉｃａｔｉｏｎｏｆｖａｒｉｏｕｓｔｅｃｈ ｎｏｌｏｇｉｃａｌｌｙｕｓｅｆｕｌｆｕｎｃｔｉｏｎａｌｓｕｐｒａｍｏｌｅｃｕｌａｒｄｅｖｉｃｅｓ .1 3Ｒｅｃｅｎｔｌｙ ,ｃｏｎｓｉｄｅｒａｂｌｅｅｆｆｏｒｔｓｈａｖｅｂｅｅｎｄｅｖｏｔｅｄｔｏｃｒ…
|
Synthesis and Crystal Structure of a Novel Hydrogen‐Bonded Three‐Dimensional Polymer [Zn (1,4‐benzenedicarboxylate) ‐(pyridine)·H2O]n |
| |
| WANG,Rui-Hu HONG,Mao-Chun WENG,Jia-Bao CAO,Rong LUO,Jun-HuaState Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian ,China.Synthesis and Crystal Structure of a Novel Hydrogen‐Bonded Three‐Dimensional Polymer [Zn (1,4‐benzenedicarboxylate) ‐(pyridine)·H2O]n[J].Chinese Journal of Chemistry,2002,20(10):1124-1128. |
| |
| Authors: | WANG Rui-Hu HONG Mao-Chun WENG Jia-Bao CAO Rong LUO Jun-HuaState Key Laboratory of Structural Chemistry Fujian Institute of the Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian China |
| |
| Institution: | WANG,Rui-Hu HONG,Mao-Chun WENG,Jia-Bao CAO,Rong LUO,Jun-HuaState Key Laboratory of Structural Chemistry,Fujian Institute of the Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
| |
| Abstract: | A zinc(II) complex Zn(bdc)(py)·H2O]a (bdc=1,4‐benzenedicarboxylate, py=pyridine) has been prepared and characterized. Single crystal X‐ray diffraction analysis reveals that the complex crystallizes in the monoclinic space group P21/n with a = 0.84823(3), b = 0.91440(3), c = 1.65141(2) ran, β = 91.243(2)°, V= 1.28057(6) nm3, Z = 4. The coordination geometry at each Zn(II) center is a distorted tetrahedron. Two independent bdc ligands in a herringbone pattern link alternatively four‐coordinated Zn(II) centers into a one‐dimensional polymeric chain. Hydrogen bonds among coordinated water molecules and uncoordinated oxygen atoms of two independent bdc ligands from different polymeric chains extend one‐dimensional polymeric chains into a three‐dimensional structure. |
| |
| Keywords: | crystal structure 1 4-benzenedicarboxylate zinc(II) polymer hydrogen bonding |
| 本文献已被 CNKI 等数据库收录！ |
|
