Spectral reflectance of the one-dimensional organic metals (perylene)2(PF6)1.1 × 0.8CH2Cl2 and (perylene)2(AsF6)1.1 × 0.7CH2Cl2 |
| |
Authors: | R Wilckens HP Geserich W Ruppel P Koch D Schweitzer HJ Keller |
| |
Institution: | Institut für angewandte Physik der Universität, D-7500 Karlsruhe, West Germany;Max-Planck-Institut für medizinische Forschung, Abteilung für molekulare Physik, D-6900 Heidelberg, West Germany;Anorganisch-chemisches Institut der Universität, D-6900 Heidelberg, West Germany |
| |
Abstract: | We report on the optical reflectance of (perylene)2(PF6)1.1 × 0.8CH2Cl2 and (perylene)2(AsF6)1.1 × 0.7CH2Cl2 single crystals in the energy range from 0.25 to 4 eV. For light polarized perpendicular to the molecular stacks the crystals exhibit the optical behaviour of an insulating molecular crystals, whereas for light polarized parallel to the stacks a pronounced plasma edge at is observed. The experimental data were analyzed by a Lorentz-Drude model in order to determine the electrical conductivity, the carrier concentration, the effective mass, the collision time, the band width, and the Fermi vector of the crystals. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|