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Solvent extraction of uranium(VI) and separation of vanadium(V) from sulfate solutions using Alamine 336
Authors:Jyothi Rajesh Kumar  Joon-Soo Kim  Jin-Young Lee  Ho-Sung Yoon
Institution:(1) Metal Recovery Department, Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources (KIGAM), 92 Gwahang-no, Yuseong-gu, Daejeon, 305-350, Republic of Korea;
Abstract:The present scientific study on uranium(VI) solvent extraction and vanadium(V) separation from sulfate solutions using Alamine 336 as an extractant diluted in kerosene was established. The preliminary experiments indicating the uranium extraction process will follow the solvation as well as ion-exchange mechanisms. In the present acid region (0.1–1.0 mol dm−3 H2SO4) it showing the ion-exchange type mechanism. Time (1–120 min) and temperature (25–55 °C) not influencing the present extraction system. Other experimental parameters like loading capacity of Alamine 336, stripping of uranium from loaded organic phase, recycling of Alamine 336 and separation of uranium(VI)/vanadium(V) was studied.
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