Solvent extraction of uranium(VI) and separation of vanadium(V) from sulfate solutions using Alamine 336 |
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Authors: | Jyothi Rajesh Kumar Joon-Soo Kim Jin-Young Lee Ho-Sung Yoon |
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Institution: | (1) Metal Recovery Department, Mineral Resources Research Division, Korea Institute of Geoscience and Mineral Resources (KIGAM), 92 Gwahang-no, Yuseong-gu, Daejeon, 305-350, Republic of Korea; |
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Abstract: | The present scientific study on uranium(VI) solvent extraction and vanadium(V) separation from sulfate solutions using Alamine
336 as an extractant diluted in kerosene was established. The preliminary experiments indicating the uranium extraction process
will follow the solvation as well as ion-exchange mechanisms. In the present acid region (0.1–1.0 mol dm−3 H2SO4) it showing the ion-exchange type mechanism. Time (1–120 min) and temperature (25–55 °C) not influencing the present extraction
system. Other experimental parameters like loading capacity of Alamine 336, stripping of uranium from loaded organic phase,
recycling of Alamine 336 and separation of uranium(VI)/vanadium(V) was studied. |
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