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具可调光学性质的富勒烯聚合物
引用本文:彭汉 梁淑美. 具可调光学性质的富勒烯聚合物[J]. 高分子学报, 1997, 0(3): 314-318
作者姓名:彭汉 梁淑美
作者单位:香港科技大学化学系
摘    要:聚(C60 甲基丙烯酸甲酯)与聚(C60 苯乙烯)的THF溶液的透射光谱随浓度的增大而不断红移.这种异常的光谱位移可能与富勒烯的纳级(10-9)簇的形成有关.用简单的办法来“调改”一物质的性质是科学家们长期梦寐以求的,而含C60的聚合物正代表了这一群新奇的物质,它们的光学性质可以预期地和可逆地调变,只要简单改变一下浓度.

关 键 词:富勒烯聚合物,C_(60)-苯乙烯共聚物,C_(60)-MMA共聚物,光学聚合物,光透射,致色效应

FULLERENE POLYMERS WITH TUNABLE OPTICAL PROPERTIES
PENG Han, LIANG Shu Mei, TANG Benzhong. FULLERENE POLYMERS WITH TUNABLE OPTICAL PROPERTIES[J]. Acta Polymerica Sinica, 1997, 0(3): 314-318
Authors:PENG Han   LIANG Shu Mei   TANG Benzhong
Abstract:Light transmission spectra of THF solutions of poly(C 60 co methyl methacrylate)s and poly (C 60 co styrene)s continuously red shift with increasing concentration.Formation of fullerene nanoclusters may be responsible for the unusual spectral shift with concentration.It has long been scientists′ dream to “tune” material′s properties by simple means,and the C 60 containing polymers represent such a group of novel materials whose optical properties are predictably and reversibly tunable by a simple change in concentration.
Keywords:Fullerenne polymers  C 60 styrene copolymers  C 60 MMA copolymers  Optical polymers  Light transmission  Chromic effects  
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