Luminescence in Organic Silicons Prepared from Organic Precursors in Plasma Discharges |
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Authors: | Pavel Horváth František Schauer Ivo Kuřitka Ota Salyk Martin Weiter Norbert Dokoupil Stanislav Nešpůrek Vlastimil Fidler |
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Institution: | (1) Faculty of Chemistry, Brno University of Technology, CZ-61200 Brno, Czech Republic,;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, CZ-16206 Prague, Czech Republic,;(3) Faculty of Nuclear Sciences, Czech Technical University, CZ-11519 Prague, Czech Republic, |
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Abstract: | Summary. The photoluminescence of plasma-prepared polysilanes during the change from linear 1D Si chains to an amorphous 3D Si network
was studied. The excitonic absorption band with a maximum at 353 nm in 1D Si experiences a blue shift and broadening upon
introduction of branching and networking defects. With the gradual transition from 1D to 3D structure, an extensive redistribution
of oscillator intensity along the absorption edge, accompanied by a decrease of the resolution of the σ-σ* band, was observed. In the short wavelength region of the excitation spectra there is an enormous increase of excitonic emission
at 328 nm. This effect is tentatively attributed to the excitation of the phenyl group or to the phenyl-silicon bond as confirmed
by effusion spectra of the phenyl species.
Received July 10, 2000. Accepted (revised) September 8, 2000 |
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Keywords: | , ,Silicon polymers, Plasma polymers, Luminescence, Effusion, |
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