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Unusual conversion of substituted-3-formylchromones to 3-(5-phenyl-3H-[1,2,4]dithiazol-3-yl)chromen-4-ones: a facile and efficient route to novel 1,2,4-dithiazoles
Authors:Tilak Raj  Vivek Gupta  Priyanka Kanwal
Institution:a Bio-Organic and Photochemistry Laboratory, Department of Pharmaceutical Sciences, Guru Nanak Dev University, Amritsar 143 005, Punjab, India
b P.G. Department of Physics, University of Jammu, Jammu Tawi 180 006, India
c Department of Chemistry, Guru Nanak Dev University, Amritsar 143 005, Punjab, India
Abstract:Substituted 3-formylchromones react with 2-phenyl-4-dimethylamino-1-thia-3-azabuta-1,3-diene (4) or thio-benzamide (7) by heating their toluene solution in a sealed tube to give novel substituted 3-(5-phenyl-3H-1,2,4]dithiazol-3-yl)chromen-4-ones (6a-e) in high yields.
Keywords:Dithiazoles  3-Formylchromones  Thio-azadiene  Thio-benzamide
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