Adamantylation of nitro-substituted aromatic amines in protic acids |
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| Authors: | S. B. Volkova O. V. Platonova V. G. Tsypin V. A. Polukeev |
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| Affiliation: | (1) Applied Chemistry Russian Research Center, pr. Dobrolyubova 14, St. Petersburg, 197198, Russia;(2) Vekton Ltd., St. Petersburg, Russia |
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| Abstract: | Adamantylation of mono-and dinitro-substituted aromatic amines in sulfuric and phosphoric acids and in a mixture of phosphoric and acetic acids gives mainly the corresponding N-adamantyl derivatives. The results of kinetic measurements showed reversible character of the process. |
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