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Chiral Cu(II) complex catalyzed enantioselective addition of phenylacetylene to N-aryl arylimines
Authors:Bao Liu   Ling Huang   Juntao Liu   Yao Zhong   Xingshu Li  Albert S.C. Chan  
Affiliation:

aSchool of Pharmaceutical Science, Sun Yat-Sen University, Guangzhou 510006, China

bOpen Laboratory of Chirotechnology of the Institute of Molecular Technology for Drug Discovery and Synthesis and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China

Abstract:Chiral tridentate N-tosylated aminoimine ligands were used in the Cu(II)-catalyzed enantioselective addition of phenylacetylene to N-aryl arylimines, affording products up to 92% ee.
Keywords:
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