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Dynamics of pulsed recording of holographic diffraction gratings in photopolymer materials
Authors:V. V. Shelkovnikov  E. V. Vasil’ev  T. N. Gerasimova  E. F. Pen  A. I. Plekhanov
Affiliation:(1) Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia;(2) Institute of Automatics and Electrometry, Siberian Division, Russian Academy of Sciences, Universitetskii pr. 1, Novosibirsk, 630090, Russia
Abstract:The dynamics of recording holographic diffraction gratings in photopolymer material using 10-ns pulses of Nd:YAG laser radiation (532 nm) was investigated. The formation of permanent and intermediate gratings was observed. Optimization of the photopolymer composition for pulsed recording was performed. The kinetic photopolymerization models taking into account the mechanisms of radical destruction due to recombination and by impurities are verified. Measurement of the recording kinetics at different recording angles showed that diffusion does not affect the hologram formation for times of the same order of magnitude as the recording duration (0.1 s) at a length of the grating half-period. Samples of the photopolymer composition in triethanolamine were investigated and diffusion of oligomeric acrylamide molecules was revealed. The diffusivity was found to be 1.1 × 10?9 cm2/s.
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