(5R,6S,5′R,6′S)-5,6,5′,6′-Diepoxy-β,β-cartin: Sythese,Spectroskopische, chiroptische und chromatographische Eigenschaften |
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Authors: | Murat Acemoglu Conrad Hans Eugster |
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Institution: | Organisch-chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH–8057 Zürich |
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Abstract: | (5R,6S,5′R,6′S)-5,6,5′,6′-Diepoxy-β,β-Carotene: Synthesis, Spectroscopical and Chiroptical Properties, and HPLC-Behaviour Using the scheme C13 + C2→C15 + C10→C40, whereby C13 = (5R,6S)-5,6-epoxy-β-ionone 8], the title compound 11a , (R = H), has been prepared and characterized. It exhibits nearly identical CD spectra as violaxanthin ( 11b , R = OH). |
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